Serveur d'exploration H2N2

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On the equilibrium between the solid phase and the gas phase of the systems hydrogen-nitrogen, hydrogen-carbon monoxide and hydrogen-nitrogen-carbon monoxide

Identifieur interne : 002D43 ( Main/Exploration ); précédent : 002D42; suivant : 002D44

On the equilibrium between the solid phase and the gas phase of the systems hydrogen-nitrogen, hydrogen-carbon monoxide and hydrogen-nitrogen-carbon monoxide

Auteurs : Z. Dokoupil [Pays-Bas] ; G. Van Soest [Pays-Bas] ; M. D. P. Swenker [Pays-Bas]

Source :

RBID : ISTEX:5E1EE7104134165AF62DFF5FDF235B59C1FA7FDC

English descriptors

Abstract

Summary: The equilibrium between the solid and gas phases has been studied, using the flow method. The pressure varied from 1.3 atm up to 50 atm. The composition of the gas phase has been determined by means of the solidification of N2 (or CO) with the aid of liquid hydrogen. The most favourable conditions for the purification of hydrogen were deduced from the experimental results with respect to the binary mixtures H2−N2 and H2−CO. The agreement between theory and experiments proved to be satisfactory. The behaviour of the ternary mixture H2−N2−CO is shown in the corresponding diagrams.

Url:
DOI: 10.1007/BF03184616


Affiliations:


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Le document en format XML

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<term>Actual behaviour</term>
<term>Analysis procedure</term>
<term>Analytical apparatus</term>
<term>Approximate solution</term>
<term>Atrn</term>
<term>Binary</term>
<term>Binary mixture</term>
<term>Binary mixtures</term>
<term>Binary system</term>
<term>Binary systems</term>
<term>Bourdon gauge</term>
<term>Capillary tube</term>
<term>Carbon monoxide</term>
<term>Certain pressure</term>
<term>Characteristic behaviour</term>
<term>Circulation method</term>
<term>Coefficient</term>
<term>Combination rules</term>
<term>Complete solubility</term>
<term>Concentration scale</term>
<term>Concentration table</term>
<term>Condensable</term>
<term>Condensable component</term>
<term>Condensable components</term>
<term>Condensable fraction</term>
<term>Condensed nitrogen</term>
<term>Condensed phase</term>
<term>Connodal</term>
<term>Connodal line</term>
<term>Connodal lines</term>
<term>Consistent results</term>
<term>Constant pressure</term>
<term>Constant temperature</term>
<term>Constituent components</term>
<term>Corresponding curves</term>
<term>Corresponding diagrams</term>
<term>Corresponding points</term>
<term>Critical line</term>
<term>Critical point</term>
<term>Critical points</term>
<term>Critical pressure</term>
<term>Critical temperature</term>
<term>Cryostat</term>
<term>Cubic term</term>
<term>Dewar vessel</term>
<term>Diagram</term>
<term>Different phases</term>
<term>Dokoupil</term>
<term>Enhancement</term>
<term>Enhancement factor</term>
<term>Equilibrium</term>
<term>Equilibrium curves</term>
<term>Equilibrium diagrams</term>
<term>Equilibrium surfaces</term>
<term>Equilibrium vessel</term>
<term>Experimental curves</term>
<term>Experimental data</term>
<term>Experimental point</term>
<term>Experimental points</term>
<term>Experimental results</term>
<term>Experimental values</term>
<term>Flow method</term>
<term>Flow process</term>
<term>Gibbs function</term>
<term>High pressure</term>
<term>Higher pressures</term>
<term>Higher temperatures</term>
<term>Homogeneous region</term>
<term>Homogeneous system</term>
<term>Horizontal axis</term>
<term>Hydrogen axis</term>
<term>Hydrogen systems</term>
<term>Hydrostatic pressure</term>
<term>Inhomogeneous</term>
<term>Inhomogeneous region</term>
<term>Initial composition</term>
<term>Initial concentration</term>
<term>Initial mixture</term>
<term>Integration constants</term>
<term>Isobar</term>
<term>Kamerlingh onnes</term>
<term>Large quantity</term>
<term>Linear term</term>
<term>Linear theory</term>
<term>Liquid hydrogen</term>
<term>Liquid phase</term>
<term>Logarithmic scale</term>
<term>Lower pressures</term>
<term>Maximum number</term>
<term>Mercury level</term>
<term>Mercury manometer</term>
<term>Molar volume</term>
<term>Mole fraction</term>
<term>Mole fractions</term>
<term>Monoxide</term>
<term>Monoxide isobar</term>
<term>Move downwards</term>
<term>Nitrogen</term>
<term>Numerical evaluation</term>
<term>Optimal pressure</term>
<term>Other hand</term>
<term>Partial pressure</term>
<term>Partial pressure mmhg</term>
<term>Phase equilibrium</term>
<term>Phys</term>
<term>Platinum thermometer</term>
<term>Pressure range</term>
<term>Previous section</term>
<term>Pure component</term>
<term>Pure components</term>
<term>Pure hydrogen</term>
<term>Pure nitrogen</term>
<term>Quadratic</term>
<term>Relative concentration</term>
<term>Remarkable shift</term>
<term>Satisfactory agreement</term>
<term>Second virial coefficient</term>
<term>Several phases</term>
<term>Small quantities</term>
<term>Soest</term>
<term>Solid nitrogen</term>
<term>Solid phase</term>
<term>Solid state</term>
<term>Space figure</term>
<term>Static method</term>
<term>Stopcock</term>
<term>Storage cylinder</term>
<term>Straight line</term>
<term>Sublimation curve</term>
<term>Swenker</term>
<term>Swenker chapter</term>
<term>Swenker table</term>
<term>System hydrogennitrogen</term>
<term>System monoxide</term>
<term>Temperature dependence</term>
<term>Ternary</term>
<term>Ternary mixture</term>
<term>Ternary system</term>
<term>Ternary system monoxide</term>
<term>Theoretical approach</term>
<term>Theoretical calculations</term>
<term>Theoretical predictions</term>
<term>Total pressure</term>
<term>Triple point</term>
<term>Univariant equilibrium</term>
<term>Upper curve</term>
<term>Vapour</term>
<term>Vapour phase</term>
<term>Vapour pressure</term>
<term>Vapour pressure curve</term>
<term>Vertical axis</term>
<term>Virial</term>
<term>Volumetric method</term>
<term>Whole amount</term>
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<div type="abstract" xml:lang="en">Summary: The equilibrium between the solid and gas phases has been studied, using the flow method. The pressure varied from 1.3 atm up to 50 atm. The composition of the gas phase has been determined by means of the solidification of N2 (or CO) with the aid of liquid hydrogen. The most favourable conditions for the purification of hydrogen were deduced from the experimental results with respect to the binary mixtures H2−N2 and H2−CO. The agreement between theory and experiments proved to be satisfactory. The behaviour of the ternary mixture H2−N2−CO is shown in the corresponding diagrams.</div>
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